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These instructions assume you have opened Microsoft Office Outlook 2007 before and are changing settings in an email account that has already been configured in the program. If you are setting up a new account, follow the steps in the account creation wizard which should run automatically upon running the program for the very first time. The information the wizard will require is provided in various fields below.
The following screenshots were taken from Microsoft Office Outlook 2007 running on Windows Vista.

zimbraserver.autoexec.net in the text field next to Incoming mail server.zimbraserver.autoexec.net in the text field next to Outgoing mail server (SMTP).